by Sara McCaslin, PhD Sara McCaslin, PhD No Comments

Machined and Molded Polymer Bearings: Nylon 66, PEEK, and PPS

Nylon 66, PEEK, and PPS are available in bearing grades, but how should they be manufactured? The choice of manufacturing method can have a significant impact on their tolerances, performance, and cost. 

This blog post focuses on machined and molded polymer bearings, including their benefits and limits, how they compare to metal options, and the best ways of manufacturing bearings made from three very different materials: Nylon 66, PEEK, and PPS. 

Introduction to Polymer Bearings

Polymer bearings are low-friction, lightweight alternatives to traditional bearings. They are corrosion-resistant and offer varying degrees of chemical resistance. Polymer bearings are also known for their ability to run dry or with minimal lubrication, as well as good wear characteristics. They are also electrically insulating and offer quieter operation than their metal counterparts.

However, polymer bearings do have their limits. They are more susceptible to thermal expansion and may have lower load limits and PV than their metal counterparts, but the addition of fillers can mitigate this issue. In some cases, they may be susceptible to moisture uptake. 

The table below summarizes the major differences between metal and polymer bearings.

Metal vs Polymer Bearings

FeatureMetal BearingsPolymer Bearings
FrictionLow only with lubricationLow due to inherent lubricity
LubricationRequiredOften not required
Wear MechanismAbrasive/adhesive fatigueTransfer film formation
CorrosionPossibleNearly immune
Shock/VibrationNo dampingNatural damping
SpeedHighModerate
LoadHigherModerate
Temperature LimitsExcellentVaries by polymer
MaintenanceHigherVery low

Machined vs. Molded Polymer Bearings

Machined bearings are best for small production runs where tight tolerances and complex geometries are involved, and machining is ideal for prototypes, custom components, and specialty rotating equipment. This approach to manufacturing bearings also allows the material to remain homogenous with no molded-in stresses.

Molded bearings are the best option for high-volume production, and they are more cost-effective for simpler geometries. Molding also means reduced part-to-part variation; however, molded-in stress may be present, and there are limits to surface finish.

When choosing between machined and molded polymer bearings, the key factors are:

  • Geometry
  • Tolerances
  • Cost
  • Production volume

Nylon 66, PEEK, and PPS

Among the various options for polymer bearings are Nylon 66, PPS, and PEEK. The table below summarizes the differences between these materials.

Performance Comparison: Nylon 66 vs. PPS vs. PEEK

Property / FactorNylon 66PPSPEEK
Max Continuous Use Temperature~100–120°C~200–220°C~240–260°C
Wear ResistanceGood (improved with lubrication)Very goodExcellent (especially filled grades)
FrictionLowLowVery low
Moisture AbsorptionHigh (can swell, affects tolerances)Very lowVery low
Dimensional StabilityModerate (affected by humidity)HighVery high
Chemical ResistanceModerateExcellentExcellent
Mechanical StrengthGoodHighVery high
Impact ResistanceVery goodModerateGood
Creep ResistanceModerateGoodExcellent
PV CapabilityLow–MediumMedium–HighHigh–Very High
CostLowMediumHigh
Machining SuitabilityExcellentExcellentExcellent (best with filled grades)
MoldabilityExcellentGoodGood
Typical ApplicationsRollers, appliance bearings, automotive interior componentsPumps, compressors, chemical processing, precision housingsAerospace, oil & gas, high-speed bearings, semiconductor tools

Manufacturing Nylon 66, PEEK, and PPS Bearings

There are several different bearing materials available, but of interest in this blog post are Nylon 66, PPS, and PEEK bearings.

Nylon 66

Nylon 66 is very easy to mold because of its low viscosity, forging processing window, and good flow characteristics. However, there is going to be high mold shrinkage, which requires careful part design to keep warpage under control. Nylon also absorbs moisture, which means that drying is important before molding takes place. 

Nylon also machines easily, but its high ductility leads to stringy chips that necessitate the use of chip-breakers. Heat buildup is also an issue with nylon, and moisture absorption can impact the level of precision that can be achieved. It does, however, respond well to secondary machining on already molded parts, but does not work well with tight-tolerance CNC components.

PEEK

Because PEEK high a high melt temperature around 343°C, a very narrow thermal window that requires precision temperature control, and requires a heated mold, it is considered challenging to mold. However, with the right processing parameters and careful design, PPS can be molded and can manufacture parts with excellent thermal and mechanical performance (but is more expensive). 

PEEK is very difficult to machine. Its high modulus and hardness make it especially tough on cutting tools, and reinforced grades can be highly abrasive. It also generates an abundance of heat, thus requiring the use of coolants. However, machining PEEK supports excellent tolerances and surface finishes when the right combination of feed and speed is used. In fact, PEEK is frequently machined for low-volume aerospace and medical components.

PPS

PPS is not as easy to mold as Nylon 66 because its melt temperature is higher, it possesses a narrower processing window, and has high viscosity. However, it does exhibit very low shrinkage and excellent dimensional stability. PPS molding is very predictable and an excellent option once the right processing parameters have been figured out.

PPS is machinable, definitely more so than Nylon, but tends to be more brittle. It produces short chips and there is a risk of edge chipping during more aggressive cuts. On the other hand, it is good for tight tolerances. Note that filled grades of PPS can accelerate tool wear. Machining PPS is ideal for high-precision parts where dimensional stability is important.

Conclusion

Machined and molded Nylon 66, PPS, and PEEK bearings continue to gain traction because of properties such as low friction, wear characteristics, damping, corrosion resistance, and chemical compatibility. If you are in need of polymer bearings, Advanced EMC is here to help. Our team of engineers and bearing experts can help you from initial design to manufacturing to testing. Contact us today to learn more.

by Denise Sullivan Denise Sullivan No Comments

Exploring the World of PEEK Advanced Polymer Unveiling the Wonders of PEEK Material and its Polymerization Process

In the world of advanced polymers, one material that stands out for its exceptional properties and versatility is PEEK. Polyether ether ketone (PEEK) is a high-performance thermoplastic polymer that has revolutionized various industries due to its unique combination of mechanical, thermal, and chemical properties. PEEK has found its way into countless products and technologies, from aerospace to medical applications. This article will delve deep into the world of PEEK advanced polymer, exploring its characteristics, applications, and the fascinating process behind its polymerization.

PEEK Advanced Polymer

What is PEEK?

PEEK is a semi-crystalline thermoplastic belonging to the polyaryletherketones family (PAEK). It was first developed in 1978 by Victrex plc., a leading manufacturer of high-performance polymers. The molecular structure of PEEK consists of repeating units containing an aromatic ketone group connected by ether linkages. This unique structure gives rise to remarkable properties that set it apart from other polymers.

Key Characteristics of PEEK

  • High-Temperature Resistance: One of the most impressive features of PEEK is its ability to withstand extreme temperatures without losing its mechanical integrity. It can operate continuously at temperatures up to 250°C (482°F) with short-term excursions up to 300°C (572°F), making it suitable for demanding applications where conventional plastics would fail.
  • Excellent Chemical Resistance: Another notable property of PEEK is its resistance to various chemicals, including acids, bases, solvents, oils, and greases. This makes it an ideal choice for environments where exposure to corrosive substances is expected.
  • Mechanical Strength: Despite being lightweight compared to metals, PEEK exhibits exceptional mechanical strength and rigidity. It has a high tensile strength and modulus of elasticity, making it suitable for load-bearing applications.
  • Low Friction Coefficient: PEEK has a low friction coefficient, similar to PTFE (polytetrafluoroethylene). This property makes it an excellent choice for applications requiring reduced wear and friction, such as bearings and seals.
  • Biocompatibility: PEEK is biologically inert and does not elicit adverse reactions when in contact with human tissues or bodily fluids. This biocompatibility makes it ideal for medical implants and devices.

The Polymerization Process

The synthesis of PEEK involves a two-step process: nucleophilic substitution reaction followed by polycondensation. Let’s explore each step in detail:

Nucleophilic Substitution Reaction

In the first step, 4,4’-difluorobenzophenone (DFBPA) reacts with bisphenol-A (BPA) in the presence of an alkali metal base catalyst such as potassium carbonate (K2CO3). This reaction leads to the intermediate diphenyl ether ketone (DPEK) formation.

Chemical Equation:

DFBPA + 2 BPA + 2 K2CO3 → DPEK + 4 KF + CO2

Polycondensation

The second step involves the polycondensation reaction, where DPEK undergoes further polymerization to form long chains of PEEK. This process is typically carried out under high temperatures (>300°C) and vacuum conditions to facilitate the removal of volatile by-products.

Chemical Equation:

n DPEK → [PEEK]n + n phenol

It is important to note that water molecules are generated as a by-product during this process, which can hinder molecular weight development if it is not removed effectively.

Applications of PEEK

Due to its exceptional properties, PEEK has found widespread use in various industries. Let’s explore some of its critical applications:

Aerospace and Defense

PEEK is widely used in aerospace and defense due to its lightweight nature, high strength, and chemical resistance. It is used in components such as brackets, connectors, seals, and electrical insulation.

Oil and Gas

The oil and gas industry relies on materials that can withstand harsh environments. PEEK’s chemical resistance and high-temperature stability suit it for downhole applications like seals, bushings, valves, and pump components.

Medical Devices

PEEK is extensively used in the medical field due to its biocompatibility and sterilizability. It finds applications in orthopedic implants (such as spinal cages), surgical instruments, dental tools, and prosthetics.

Automotive

Due to its flame-retardant properties, in the automotive industry, PEEK is utilized for various purposes, including electrical connectors, fuel system components (such as sensors), gears, bearings, bushings, and interior trims.

Electronics

PEEK’s excellent dielectric properties make it a preferred choice for electrical insulation applications such as connectors and insulating tapes. Its ability to withstand high temperatures makes it suitable for electronic device housings.

PEEK advanced polymer has proven to be a game-changer in various industries due to its exceptional properties and versatility. From aerospace to medical applications, its ability to withstand high temperatures, resist chemicals, and maintain mechanical strength makes it an ideal choice for demanding environments. The polymerization process behind the creation of PEEK involves nucleophilic substitution reactions followed by polycondensation. With its wide range of applications and continuous advancements in manufacturing techniques like 3D printing, the future looks bright for this remarkable material.

Frequently Asked Questions (FAQs)

  1. Is PEEK recyclable?
    Yes! PEEK can be recycled through methods like pyrolysis or mechanical recycling processes.
  2. What are the limitations of using PEEK?
    While highly versatile, there are a few limitations to using PEEK. It comes at a higher cost compared to conventional plastics. Additionally, machining or processing it can be challenging due to its high melting point.
  3. Can PEEK be 3D printed?
    Yes! With technological advancements, especially selective laser sintering (SLS) and fused deposition modeling (FDM), PEEK can be successfully 3D printed.
  4. Is PEEK FDA-approved for medical applications?
    PEEK has received FDA approval for various medical applications, including orthopedic implants and surgical instruments.
  5. What are the advantages of using PEEK over metals?
    Using PEEK instead of metals offers several advantages, such as weight reduction, corrosion resistance, electrical insulation properties, and easier processing and machining.