by Sara McCaslin, PhD Sara McCaslin, PhD No Comments

The Basics of PVDF

Kynar PVDF (property of Arkema) is a high purity polymer that combines extreme-temperature performance, easy manufacturability, and durability in some of the harshest environments. 

What is PVDF?

PVDF (polyvinylidene difluoride or polyvinyl fluoride) is a fluorinated thermoplastic resin that is classified as a specialty polymer whose brand names include Kynar (Arkema), KF (Kureha), and Solef or Hylar (Solvay). This engineering polymer can often be found in environments that involve high purity, hot acid, extremely high temperatures, and/or radiation. 

Where is PVDF Used?

PVDF is used extensively in a wide range of industries. Semiconductor manufacturing makes use of PVDF’s ultra-pure status and its ability to perform in harsh environments that may involve extreme temperatures and aggressive chemicals. Electronics and electricity applications depend on PVDF’s outstanding low smoke emission and fire-resistant properties along with electrical properties for use as wiring insulation.

PVDF’s ability to handle radiation makes it an excellent choice for nuclear waste handling, and its high-temperature performance and chemical compatibility lends itself readily to the oil and gas industry. Because PVDF has excellent high-temperature performance, high purity, and low permeability, excellent strength, and chemical compatibility, it is used extensively in chemical processing.

Purity and FDA approval have made it a popular choice in food and beverage packaging and processing as well as pharmaceutical processing. It is often used in connection with water and wastewater management for similar reasons. PVDF is also used extensively in the medical market and healthcare industry where it is used as a biomaterial for medical textiles, such as hernia meshes, as well as for medical sutures.

The transportation and energy market has begun using PVDF as a binder for cathodes and anodes in HEV/EVs (Hybrid Electric Vehicle/Electric Vehicle). Its chemical compatibility and anti-corrosion properties make it useful as a barrier liner for fuel lines and tanker trailer lines. Aviation also makes ample use of PVDF for wiring harnesses and general coatings

How is PVDF Used?

PVDF is commonly used for several specific types of applications across industries:

  • Pump assemblies
  • Heat exchangers
  • Tanks and vessels
  • Nozzles
  • Sensors and actuators
  • Fittings, pipes, tubing, and valves
  • Membranes, including microfiltration membranes
  • Filters and filter housings
  • Liners and films
  • Cable jacketing and harnessing
  • Biocompatible materials

Key Properties of PVDF

As alluded to in previous sections, PVDF possesses several features of interest to engineers:

  • Extremely high purity with low permeability
  • FDA compliant and non-toxic
  • Excellent heat resistance and thermal stability 
  • Good mechanical properties
  • Resistant to a wide range of aggressive chemicals
  • Resistant to UV exposure, ozone oxidation reactions, and radiation
  • Resistant to the growth of microorganisms
  • Excellent burn characteristics 
  • Good manufacturability
  • One of the lowest melting points of commercial fluoropolymers
  • Excellent electrical properties
  • Excellent abrasion resistance
  • Low density (1.78 gm/cm3)
  • Recyclable

In addition, PVDF offers excellent abrasion resistance, is lightweight, and can be recycled. Also, note that there are additives available for PVDF to enhance its properties and its melt processability.

Purity and FDA Compliance

In addition to being an extremely high purity polymer, PVDF is both FDA compliant and non-toxic while exhibiting very low gas and liquid permeability.

Heat Resistant and Thermal Stability

One of the outstanding features of PVDF lies in its excellent performance, chemical stability, and dimensional stability in high-temperature environments with a service temperature rating of up to 300 F.

Mechanical Properties

Among the outstanding mechanical properties possessed by PVDF are good deflection, tension, compression, and torsion when compared to other fluorinated polymers. In addition, its low rate of water absorption (0.4%) means that it will remain dimensionally stable (not swell) when in a moisture-rich environment. In addition, PVDF has excellent impact strength.

Chemical Compatibility

PVDF is known for its excellent chemical compatibility that includes weak and strong acids (including mineral and organic); alcohols; aromatic and aliphatic solvents; weak bases; hydrocarbons; halogenated compounds; ionic and salt solutions; and oxidants. Its primary weaknesses are caustics, esters, strong bases, and ketones. 

Microorganism Growth

The surface of PVDF is highly resistant to the growth of microorganisms, including bacteria, fungi, and mold. It is also resistant to weathering, grime, and even graffiti (which is why it is often used in the architectural industry).

Burn Characteristics

PVDF has excellent flame and smoke properties, including UL 94 V-0 rating indicating it is both non-flammable and self-extinguishing along, or more specifically “Burning stops within 10 seconds on a vertical specimen; drips of particles allowed as long as they are not inflamed.” In addition, certain grades of PVDF also possess an excellent flame spread/smoke developed rating of 25/50 (when tested in accordance with ASTM E 84).

Manufacturability

PVDF is also highly manufacturable and melt-processable, lending itself to precision machining, rotomolding, compression molding, injection molding, and extrusion as well as subsequent welding and fabrication. Its ability to be used in molding is primarily due to its low melting point of 352 F, compared to PTFE at 621 F or FEP at 517 F.

Electrical Properties

In addition to electrochemical stability, PVDF also possesses a very high dielectric constant (280 volts per meter) and a high piezoelectric constant. In fact, it possesses both piezoelectric and pyroelectric properties.

Conclusion

One of the polymers we work with here at Advanced EMC is PVDF Kynar made by Arkema. If you are interested in Kynar, have questions about its usage and processing, or need a quote, feel free to contact us and we will have one of our experts respond right away.

by Jackie Johnson Jackie Johnson No Comments

A Growing Medical Market

There are many factors that contribute to the rapidly growing medical plastics market. There is an increased demand for advanced medical devices, a rise in disposable income and changing lifestyles, and a demand for affordable and efficient healthcare systems.

These and more are currently driving the medical market, with a current estimated net worth of 22.8 billion USD.

And it is only growing.

Experts suggest that by 2024, the market will grow to a whopping 31.7 billion, with a CAGR of 6.8%.

Medical Plastics Market

Source: Markets and Markets, Medical Plastics Market

Applications of Medical Grade Plastics

Plastic packaging is widespread across many industries, but no more so than in the medical field. Within the next few years, packaging is expected to grow at a CAGR of 7.8%, due to the increased use in pharmaceutical packaging, device packaging, and more.

Surprisingly though, it is devices such as medical implants and machinery that are generating the largest revenue and driving the industry forward. A perfect storm of an ever-growing population and an increase in chronic diseases, along with the lower manufacturing cost of these devices has led to the largest growth in the medical plastics industry.

Global medical polymers market

Source: Grand View Research, Medical Polymers Market Size

An Industry Standard

Since the 1980s plastics have dominated the medical device industry on account of their low manufacturing cost, flexibility, ease of replacement, and low risk of infection.

Plastics also provide radiolucency, enable light-weighting, and reduce stress-shielding. Because they are radiolucent, polymer-based surgical devices allow surgeons to have an unobstructed view.

All these combine to make medical-grade plastics the gold standard in the industry. Which in turn creates a very lucrative market.

In Conclusion

The medical-grade plastic industry has taken off in an incredibly short amount of time. With increasingly easy to manufacture products coupled with an ever-expanding market, the industry will only get bigger over time. Want to learn more? Contact us today! 

 

by Sara McCaslin, PhD Sara McCaslin, PhD No Comments

Medical Engineering in the Age of COVID-19

Medical Engineering in the Age of COVID-19

Due to the COVID-19 pandemic, there has been an increase in worldwide demand for thermal scanners, respirators, and ventilators. This has been accompanied by an increased need for medical disposables such as gloves, respirators, medical masks, face shields, single-use syringes, and drapes. As a result, medical engineering and manufacturing both have temporarily shifted their focus and the results are fascinating.

3D printed hand sanitizer clasp

Additive Manufacturing

Shortages of some items have led to innovative design and manufacturing, much of it involving additive manufacturing using polymer materials. For example, Old Dominion University has been 3D printing masks and mask components made from PLA and designed so that they can be easily sterilized and reused. Europe has already seen companies in the 3D printing industry volunteer their equipment and knowledge to aid in manufacturing replacement parts for critical equipment such as oxygen and respirator valves, and many other countries are doing the same thing. 

Ventilator Designs

Many countries, including the United States, are worried about a potentially deadly shortage of ventilators. Various technology firms worldwide such as Nvidia are working to design critical care devices that can be produced both quickly and inexpensively. NASA has been given permission to start production of their emergency use ventilator that can be manufactured and built quickly, with the only drawback being its limited lifespan. 

In addition, ventilator manufacturers such as Medtronic have ramped up production and publicly shared their design specifications for one of their ventilator models so others can help meet this critical need.

Innovation

Engineers all over the world are looking for ways to make the treatment of COVID-19 patients easier and safer for medical personnel. For example, engineers in the Boston area have teamed up local doctors to develop a 3D printed bracket that will hold the tube and respirator hookup together in ventilator patients. The goal is to prevent release of the COVID-19 virus into air when these connections come undone, as they often do. 

Others at Boston University are looking at polymer nasal swabs that will do a better job of collecting mucus for COVID-19 tests, which could increase the reliability of testing and help with testing material shortages. At the Oxford Institute of Biomedical Engineering, engineers are leveraging wearable technology to allow nurses to track the vitals of COVID-19 patients who are not on ventilators and thus must remain mobile to recover.

Conclusion

The COVID-19 pandemic has changed how much of the world lives, and has affected a shift in the focus of many engineers. Trademarks of this shift include the use of additive manufacturing for PPE and replacement parts for life-saving equipment, a fresh look at ventilator designs that emphasizes manufacturability and availability, and the birth of innovative approaches to medical issues related to the pandemic. And, in this midst of this, companies like Advanced EMC are still working hard to make available the right polymer seals and bearings needed for medical equipment.