by Sara McCaslin Sara McCaslin No Comments

The Case for Polymer BURs in High-Pressure Seals

Engineers are intensely frustrated when an O-ring is specified for a design and it still fails. This is likely because the O-ring needed a backup ring (BUR), not because the O-ring was not specified correctly. In fact, polymer BURs remain an underrated but critical component in many systems, in industries ranging from food to oil & gas. 

This article looks at the main problem BURs solve, the benefits of opting for polymer BURs, and commonly used polymers. 

O-Rings and Extrusion

The clearance gap is the space between mating parts where the O-ring sits. Under high pressure, the O-ring is going to behave more like a fluid than a solid. It will get forced, or flow, into the clearance gap. When the O-ring extrudes into the clearance gap, it can lead to two different failure modes: nibbling and spiral failure.  Nibbling looks like something has taken multiple small bites from the O-ring. Spiral failure refers to tearing and cracking around the circumference of the O-ring.

This type of failure is irreversible and inevitably leads to weeping or a catastrophic leak. For hydraulic systems operating at high pressure, it will either manifest as a slow leak (weeping) or a catastrophic failure.

How BURs Solve O-Ring Extrusion (and More)

A backup ring (BUR) is installed against the O-ring, downstream of the pressure, to ensure it stays within the clearance gap. In short, a BUR physically closes the clearance gap, giving the seal nowhere to migrate. This not only prevents unwanted leaks but can extend the life of a seal from cycles to years.

BURs are often used in high-temperature or high-pressure applications. BURs can also help to evenly distribute pressure in applications involving varying clearance gaps or pressure fluctuations. Additionally, BURs help to reduce the effects of wear and friction on O-rings and serve as a thermal barrier to protect them from excessive heat.

Benefits of Using Polymer BURs

There are several benefits to using polymer BURs

Extrusion prevention – They effectively fill the clearance gap between mating parts, stopping the primary elastomer seal from being forced (extruded) into that gap under pressure, which would otherwise cause premature seal failure.

Extended pressure and temperature range – By protecting the O-ring from extrusion, polymer BURs allow the overall seal assembly to withstand higher pressures and wider temperature swings than an O-ring alone could handle.

Reduced wear on the primary seal – BURs absorb mechanical stress and abrasion so that the O-ring experiences fewer issues with friction and deformation, thus extending its service life.

Design flexibility with looser tolerances – Because the BUR compensates for extrusion risk, designers can use larger clearance gaps. The use of larger clearance gaps, in turn, simplifies the machining process and reduces manufacturing cost.

Compatibility across dynamic and static applications – Different polymers (PTFE, PEEK, nylon, polyurethane, acetal) let engineers tailor the backup ring’s flexibility, hardness, and chemical resistance to match whether the seal is static, reciprocating, or rotating.

Corrosion and chemical resistance – Unlike metal backup rings, polymers can be chosen that will not corrode or react with process fluids. This facet is particularly important in chemical, oilfield, or food-grade applications.

Lightweight and cost-effective – Polymers are generally cheaper and lighter than metal without sacrificing performance in most standard pressure ranges needed for BURs.

Ease of installation – Many polymer backup rings (especially PTFE) are flexible enough to be installed without requiring the use of special tools. This is in contrast to rigid metal rings that may require more complex assembly procedures.

System reliability – By preventing extrusion-related blowouts, polymer BURs reduce the risk of unplanned downtime, leaks, or catastrophic seal failure in critical systems like hydraulics, pneumatics, and downhole tools.

In short, polymer BURs let engineers push seal assemblies harder in terms of more pressure, wider gaps, tougher environments. And they do so while protecting the seal from the system.

Backup Ring Materials

When choosing a BUR material, ensure it is harder than the seal material to effectively prevent migration. They must also have lower coefficients of expansion than the seal and are engineered to be both rigid and tough. 

Polymer BURs are often used in place of elastomeric versions because they offer significantly better resistance to extrusion, deformation, and chemical exposure, as well as reduced long-term creep under high pressure.

Commonly used polymers include ….

Material Temp Range Chemical Resistance Friction Extrusion Resistance Cost Best Use Case
PTFE (virgin/filled) -70°F to 575°F Excellent
nearly universal
Very Low Good
better filled
Moderate High-temp, chemically aggressive, low-friction dynamic seals
PEEK -50°F to 590°F Excellent Moderate Excellent
highest strength
High High-pressure, large extrusion gaps, oilfield/downhole
Nylon (PA) -40°F to 180°F Fair to Good Moderate Good Low General-purpose hydraulics, cost-sensitive designs
Polyurethane (PU/AU) -40°F to 210°F Good
poor w/ water/steam
Mod–High Good
flexible
Low–Mod Dynamic seals needing toughness and abrasion resistance
Acetal (POM/Delrin) -40°F to 180°F Good Low–Mod Very Good
rigid
Low–Mod Static or low-speed dynamic, tight-tolerance applications

In general, PEEK wins over PTFE based on strength and extrusion resistance at high pressure, but PTFE wins on friction and chemical universality. Nylon is more rigid and dimensionally stable than polyurethane, but polyurethane flexes better in dynamic strokes. However, polyurethane degrades faster than Nylon in wet/steam environments. Acetal is often the “in-between” choice because it is more rigid than nylon or Polyurethane, but not as chemically or thermally capable as PTFE or PEEK.

Conclusion

Polymer BURs serve as cheap insurance against otherwise expensive failures. In fact, they are almost indispensable in chemical processing, hydraulics, oil & gas, and aerospace applications. And remember: it is best to decide on the inclusion of a BUR before failure, not after. But whether you need BURs before or after design, contact Advanced EMC for help. Our sealing engineers are ready to put their experience to work for you.

by Sara McCaslin Sara McCaslin No Comments

R-410A to R-454B: What Nobody Told You About Your Seals

The HVAC/refrigeration industry in the US is still in the midst of transitioning to A2L refrigerants (R-454B, R-32, etc.) that replace R-410A. These changes are required as part of the Environmental Protection Agency’s AIM Act and its mandate of a stepped phasedown reaching 40% below baseline by 2024 and 85% by 2036. This has forced HVAC manufacturers to shift away from R-410A to lower-GWP alternatives

And with that shift has come some surprising seal failures. A piece of HVAC equipment that has worked for 15 years starts experiencing seal leaks, hardening, or swelling for the first time. This is a serious compatibility issue between low-GWP refrigerants and traditional sealing solutions.

This article looks at the causes behind these failures, the failure modes involved, and seal materials to consider in solving these issues.

A Chemistry Lesson

The mechanisms behind the new seal failures occurring with low-GWP A2L refrigerants can be explained with some rather basic chemistry. 

Loss of the R-125 Buffer 

When swapping R-410A (a 50/50 blend of R-32 and R-125) for R-454B (68.9% R-32 / 31.1% R-1234yf) or pure R-32, the solvent properties of the working fluid change significantly. R-125 acted as a flammability suppressant and modified the polar solvency of the mixture. 

Next-generation A2L blends like R-454B remove R-125 entirely, and R-1234yf is itself a smaller, more polar molecule than R-125. The shift, then, is not just R-125’s absence, but also R-1234yf’s more aggressive solvency actively driving elastomer attack. The result of switching to A2Ls has been significantly higher fluid solvency against elastomers than R-410A produced. 

Enhanced Polymer Penetration

Higher concentrations of R-32 and fluorinated alkenes (HFOs) exhibit smaller molecular sizes and higher dipole interactions, increasing their diffusion rates into elastomeric matrices.

Polyolester (POE) & Polyvinyl Ether (PVE) Synergy

In addition, A2L refrigerants in US systems typically rely on Polyolester (POE) oils. The refrigerant lowers the viscosity of the oil and enhances its ability to penetrate elastomer matrix structures. As a result, the seal fails not from the gas alone, but from the combined refrigerant-oil working fluid. 

The Three Primary Failure Modes

There are three failure modes associated with the chemical reactions just discussed: gland overfill, post-maintenance leak, and RGD (Rapid Gas Decompression). 

Excessive Swell / Gland Fill-Ratio Exceedance

Overfilled seal glands, regardless of cause, lead to issues with extrusion into clearances, increased friction on dynamic shafts/spools, nibbling, and permanent mechanical tearing. This may initially appear as a lubrication issue, but it is not. The polymer matrix is absorbing the refrigerant/oil mixture, causing volume expansions exceeding 15–20%. Note that the seal was correctly sized and installed. The volume growth occuring afterward is from chemical absorption, not from an installation or specification error.

The “Post-Maintenance” Leak

As refrigerant permeates the seal, it leaches out the low-molecular-weight plasticizers, processing aids, and cross-linking agents from the elastomer. When this happens under system pressure, the seal appears tight because of swell. However, once the system is evacuated, vented, or cycled off, the absorbed refrigerant off-gasses from the seals. This off-gassing leaves behind an elastomer that has lost volume. The seal then shrinks below its original dimensions, losing compression set and causing sudden leaks.

Rapid Gas Decompression (RGD)

Next is RGD, which is a well-established failure mode in high-pressure gas sealing (e.g., API 6A, NORSOK M-710 test protocols) that A2L refrigerants newly expose HVAC seals to because of their smaller molecular size and higher solubility. In short, A2L molecules are able to permeate high-pressure elastomeric seals. During a rapid system pump-down or sudden pressure drop, the gas trapped inside the elastomer pores expands faster than it can diffuse out. The result of RGD is internal blistering, micro-fissures, and catastrophic seal rupture from the inside out.

Compatibility is at the Core

A2L systems commonly pair with different POE oil formulations than their A1 predecessors. It is, however, key to remember that the oil in A2L refrigerants is just as much a part of the compatibility question as the refrigerant itself. Testing a seal compound against R-454B alone while ignoring the oil is only testing half the problem. 

Seal Material Considerations

The information below summarizes the most commonly used materials for HVAC seals and their performance for both R140A and A2L refrigerants.

Sealing MaterialR-410A CompatibilityA2L (R-454B / R-32) RatingPrimary Risk & Failure MechanismsEngineering Recommendation
NBR (Nitrile)Acceptable Baseline (known long-term POE extraction risk)HIGH RISKHigh extraction of plasticizers; severe shrinkage post-evacuation. Swell varies unpredictably with ACN content.Not Recommended. Replace with peroxide-cured FKM or PTFE.
HNBR (Hydrogenated Nitrile)Good / ExcellentMODERATE TO HIGHHigh swell with low-ACN grades; low-temperature flexibility loss with high-ACN grades.Requires rigorous validation per compound formulation.
FKM (Standard Bisphenol-Cured)Standard ChoiceCONDITIONALVulnerable to chemical attack by basic additives/amines in PVE oils and polar A2L mixtures.Avoid standard grades. Use low-swell peroxide-cured FKMs.
FKM (High-Fluorine / Peroxide-Cured)ExcellentGOODSignificantly reduced swell and chemical resistance against POE/PVE mixtures.Recommended for static O-rings requiring elasticity.
EPDM*Specialty UseSEVERE FAILUREIncompatible with synthetic POE/PVE lubricants, causing immediate degradation and extreme swell.Prohibited in POE/PVE lubricated systems.
PTFE / Virgin & Filled PTFE**Premium / InertEXCELLENT (BEST PRACTICE)Zero chemical absorption, zero swell, zero plasticizer extraction, immune to RGD.Best Practice. Ideal for dynamic rotary shaft seals and control valves.
Fluorosint® 500 PTFE**Premium / InertEXCELLENT (BEST PRACTICE)Synthetic mica-filled PTFE; virtually immune to RGD, chemical swell, and leaching.Superior Choice. Offers lower thermal expansion and greater deformation resistance than standard PTFE under heavy load.
Fluorolon 1065**Premium / InertEXCELLENT (BEST PRACTICE)Modified PTFE compound with high chemical inertness and zero extraction risk.Cost-effective alternative to standard virgin/filled PTFE for aggressive A2L and lubricant environments.
Polyketone (PK)**GoodEXCELLENTRigid semi-crystalline thermoplastic; non-porous structure eliminates RGD and plasticizer leaching.Eco-friendly engineering option. High wear and impact strength; best suited for anti-extrusion back-up rings or structural seal components.
PVDF (Kynar®)**GoodEXCELLENTHigh mechanical strength and creep resistance; resistant to chemically aggressive refrigerants.Recyclable engineering polymer. Ideal for rigid back-up rings, valve seats, and high-pressure containment components.

*Note on EPDM: This incompatibility predates the A2L transition and applies to ester-based lubricants generally, not to the A2L refrigerant molecule itself. 

**Thermoplastic options (PTFE, Fluorosint, Fluorolon, Polyketone, PVDF) are not elastomers and are not drop-in replacements in standard elastomeric O-ring grooves. They typically require redesign (e.g., spring-energized lip seals) or are used as backup/anti-extrusion rings.

Conclusion

As legacy systems are retrofitted for use with A2L refrigerants, it is important to consider the compatibility of both the refrigerant and its oils with the seal materials. If you are looking for an effective seal design that is resistant to the harmful effects of A2L refrigerants, talk to the seal experts at Advanced EMC. Our team is familiar with HVAC / Refrigeration seal needs and is ready to work with you from design to installation and beyond.