by Sara McCaslin Sara McCaslin 1 Comment

Why Compression Set is not Enough for High-Performance Seals

A seal is a system, not just a compound. A material can meet published compression-set, hardness, and chemical-compatibility requirements yet still fail early because the qualification plan did not reproduce the governing service conditions or establish sufficient margin across the seal, gland, and hardware tolerance stack.

High-performance sealing applications can combine elevated temperature, pressure cycling, aggressive media, long required life, and tight dimensional tolerances. Under these conditions, a single static material property rarely predicts field performance. The relevant question is whether the complete seal-and-hardware system retains enough contact pressure, extrusion resistance, and chemical stability to meet its defined leakage requirement throughout service. 

This article looks at the complications that can arise from depending too heavily on compression set when selecting a material for a high-performance seal.

The Property Everyone Tests vs. The Property That Actually Predicts Failure

The industry’s default screening test for high-performance seals is compression set because it measures how much strain an elastomer or polymer fails to recover after a sustained compressive load is removed. It is useful as a baseline for comparing materials and monitoring production batch consistency.

However, compression set does not directly measure in-service sealing force, but remains useful for assessing permanent deformation and loss of available interference after unloading. It should be interpreted alongside force-retention, environmental-aging, and assembly-level data.

A more relevant property is actually stress relaxation. When an elastomer or polymer is held at constant strain, the stress it exerts against the sealing surfaces decreases progressively over time. Even when the gland holds the seal at nominally constant deflection, the compressive counterforce can decay with time

In many static sealing applications, loss of contact force can be a primary contributor to leakage, provided that the remaining contact pressure falls below the level required by the pressure differential, media, surface condition, and the gland geometry.

Consider this: a material can look suitable on a compression set chart, but still be quietly losing its sealing force while in service. This is why premature seal failures cannot be explained by the data the design team already has.

Why This Gap Matters More as Applications Get More Demanding

In high-performance systems, such as those with elevated temperature, pressure cycling, aggressive chemical exposure, tight gland tolerances, and long required service life (often occurring simultaneously), the mechanisms that reduce contact stress accelerate, while gland clearances under pressure introduce a secondary risk: extrusion.

Whether stress relaxation, creep, or both govern depends on the boundary condition and system compliance. A rigid, fixed-depth gland more closely resembles constant-strain loading, while a compliant flange joint or spring-loaded system may permit deformation growth and load redistribution. 

Standard compression set testing is typically run under a single fixed set of conditions, and these conditions may not represent the actual thermal and chemical environment the seal experiences in service. This means that the datasheet number may not transfer to the actual service application at all.

For applications that require a predictable service life, methods that model degradation over time are increasingly used to estimate realistic storage or service life rather than relying on a single-point spec.

Qualify for the Application, Not the Spec Sheet

When you have a high-performance sealing application, a datasheet property serves as an excellent screening tool but not a guarantee of performance. When evaluating seals for demanding service, ask whether the qualification data you are looking at reflects the actual service environment, not just whether the material passed a standard test.

Want to learn how to better qualify high-performance seals? Read the second part of this article series, From Datasheet to Service Life: A Better Framework for Seal Qualification. And contact us for your sealing solution needs!

by Daniel Mays Daniel Mays No Comments

Sealing Solutions for Hydrogen Systems and the Emerging Hydrogen Economy

Sealing solutions for hydrogen systems are in high demand, and that should come as no surprise. According to Statista, the world has spent close to $600 billion U.S. dollars in direct investments in hydrogen projects involving key systems such as fuel cells, storage, electrolyzers, transportation, and industrial use. 

There is, however, a major challenge with hydrogen: while it has excellent potential as a clean energy carrier, its physical properties make it difficult to seal. 

This blog post looks at how selecting the right sealing material is one of the most consequential decisions in hydrogen system design.

What Makes Sealing Solutions for Hydrogen Systems So Challenging

There are several reasons that seals for hydrogen systems can be demanding, beginning with molecular permeation.

Molecular Permeation 

The first issue related to hydrogen sealing is molecular permeation. Hydrogen is the smallest molecule (~2.9 angstroms) currently known, and because of that, hydrogen can easily permeate through many materials. This has serious consequences for hydrogen systems, including pressure loss, ignition risk, and fugitive emissions, all of which can be very dangerous. And this eliminates most standard elastomers used for seals from consideration. 

Hydrogen Embrittlement

Another problem with sealing solutions for hydrogen systems is hydrogen embrittlement. Atomic hydrogen can diffuse into the metal lattice, thereby reducing ductility and increasing brittleness. Diffusion, in turn, leads to significant problems with fatigue cracking when cyclic pressure loadings are present and has a major impact on the choice of materials for lip material.

Temperature Extremes

Another challenge related to sealing hydrogen systems lies in the temperature range. Hydrogen is a liquid at -423°F (-253°C), the temperature at which most elastomers become brittle and lose their sealing force. However, cryogenic temperatures are not all that involved. High temperatures arise with reformers, fuel cell stacks, and hydrogen combustion, where temperatures can easily exceed 392°F (200°C). Very few materials can maintain consistent properties across this full range of temperature. 

Rapid Gas Decompression

Rapid Gas Decompression (RGD) can dissolve into elastomers under pressure. When rapid depressurization occurs, the absorbed gas will rapidly expand internally and lead to cracking, blistering, and catastrophic seal failure. This problem is especially relevant in fueling station dispensers, where pressures can cycle between 350 and 700 bar.

Purity

There can also be chemical purity requirements: fuel cells and electrolyzers are sensitive to contamination from seal extractables. In addition, standard seal compounds often contain plasticizers, fillers, or cure residues that degrade membrane performance. Because of this, the seal materials chosen must be specifiable as non-contaminating or, where applicable, FDA/USP-compliant.

Optimal Polymer Materials for Hydrogen Service

Three specific engineering polymers work extremely well in hydrogen-related applications. These materials are PTFE, PEEK, and UHMW-PE.

PTFE

The most common choice for hydrogen sealing is PTFE, or polytetrafluoroethylene. This material is known for its near-zero permeability, excellent chemical inertness, and a 200°C to +260°C service range. In addition, it is available in a non-contaminating grade with no extractables or plasticizers, making it an excellent choice for fuel cell and electrolyzer environments. PTFE also has an extremely low coefficient of friction, which extends its dynamic seal life in applications with compressors and actuators. It is also self-lubricating, making it an ideal option for applications where lubricants cannot be used. However, PTFE does have a limitation to consider: it tends to cold-flow under sustained compressive loads.

There are also filled grades of PTFE that can improve key properties. These fillers include glass fiber, carbon, graphite, and PEEK-filled PTFE grades. These can increase stiffness and improve creep resistance at the cost of a slight reduction in its chemical purity. Filled grades are recommended for static seals under high sustained loads, while virgin PTFE works best for purity-critical dynamic applications.

PEEK

PEEK, which stands for polyetheretherketone, is another engineering plastic that works extremely well in sealing solutions for hydrogen systems. It offers excellent compressive strength, making it suitable for high-pressure applications. Another benefit of PEEK is its excellent chemical resistance. It also exhibits good resistance to hydrogen permeation and maintains tight tolerances when subject to thermal cycling. In addition, it possesses a low coefficient of friction (though not as low as PTFE). The most common applications for peek include backup rings (BURs), valve seats, and structural seal components. 

UHMW-PE

UHMW-PE, or ultra-high-molecular-weight polyethylene, is one of the very few polymers that can retain their ductility at liquid hydrogen temperature. In fact, it is the standard choice for liquid LH2 seal applications in areas such as liquefaction and aerospace. UHMW-PE has a very low coefficient of friction and excellent impact toughness.  It is limited at elevated temperatures, however, and should be viewed as a cryogenic-specific material in hydrogen systems.

Conclusion

From cryogenic LH2 transform to PEM electrolysis, engineering polymers are available to provide excellent seal performance in hydrogen applications. These materials can address issues such as molecular permeation, hydrogen embrittlement, extreme temperatures, rapid gas decompression, and purity. To learn more, contact Advanced EMC and allow them to put their 100+ years of combined expertise to work for you.