PPS (polyphenylene sulfide) is a high-performance, semi-crystalline engineering polymer widely used in industries such as aerospace, automotive, electronics, and industry. It combines mechanical strength with chemical resistance and excellent thermal and dimensional stability. It has found extensive applications in replacing metals and other polymers when the performance requirements are particularly severe.
This blog post examines the molecular and structural foundations of PPS performance, its key engineering benefits, and its role in advanced applications that require reliability in harsh conditions.
PPS Fundamentals: Structure, Chemistry, and Material Properties
PPS consists of repeating para-phenylene groups linked by sulfide bridges. The backbone of this polymer is composed of benzene rings (rigid, strong) and sulfur atoms (flexible connectors, chemically resistant) that form it. The repeating pattern leads to high crystallinity (~65%), which increases strength, reduces creep, and improves wear resistance. This molecular structure is also where i gets its strength and excellent chemical resistance to problematic media such as solvents, fuels, and acids.
PPS also has a high melting point of ~285°C and can withstand continuous use temperatures of up to 220–240°C. Its glass transition temperature is typically around 90°C, and it is inherently flame-resistant, with UL 94 V-0 ratings achievable without additives.
In addition, PPS has a high modulus of elasticity, good tensile strength, excellent wear resistance, and a low moisture absorption rate of less than 0.05%. It is also electrically insulating with very stable dielectric properties.

Engineering Advantages of PPS in Harsh Environments
PPS also offers excellent advantages when used in harsh environments. As alluded to earlier, it possesses excellent chemical resistance to liquids such as strong acids, strong bases, alkalis, solvents, fuels, and hydraulic fluids. It is also resistant to automotive fluids, aerospace lubricants, steam and hot water, and most cleaning chemicals. It has proven to be an excellent choice for pump components, seals, and housings that are exposed to aggressive media.
Because of its high crystallinity and low creep, PPS is able to maintain tight tolerances, and its low coefficient of thermal expansion means it retains stability across a wide range of operating temperatures. Finally, it has been shown to outperform many other engineering plastics when it comes to precision components, including gears, valves, and compressor parts.
PPS blends with lubricants (e.g., PTFE, graphite, carbon fiber) to reduce friction and enhance wear resistance. This makes it quite effective in dry-running environments where lubricants may be impractical or impossible. Filled PPS is commonly used for automotive and industrial bearing surfaces.
PPS also exhibits consistent dielectric strength, which can be crucial for electronics and high-voltage systems. It also retains its insulating properties even after prolonged exposure to heat and chemicals. PPS is commonly used in connectors, sensors, and encapsulated electronic systems.
Applications of PPS in Advanced Systems
PPS is commonly used in many industries. For example, in the automotive and transportation industry, PPS is used in fuel system components (pumps, filters, connectors) due to hydrocarbon resistance. PPS is also found in EV and hybrid powertrain parts that demand thermal/electrical stability, and brake and clutch components where dimensional stability under load is critical.
In the aerospace and defense industries, PPS can be found in structural components, housings, and fasteners where metal replacement is advantageous. In addition, PPS composites (carbon fiber reinforced) offer high strength-to-weight ratios for aircraft interiors and UAVs. Also, flame resistance and low smoke/toxicity make PPS suitable for cabin environments.
In electronics, PPS is used in high-frequency connectors, coil bobbins, switch housings, and encapsulation materials, while PPS films and coatings provide insulation and chemical resistance in demanding circuit environments.
In industrial equipment, it is used in compressor rings, pump parts, seals, and valve seats, where PPS resists wear and chemical attack. PPS reinforced with carbon fiber or PTFE provides long-lasting service in bearings and sliding elements.
There are also some specialized applications of PPS, such as off-road and racing bikes using carbon-fiber-reinforced PPS for lightweight durability and chemical processing equipment resistant to acids, caustics, and solvents.
Conclusion
PPS is a go-to high-performance material that delivers where metals and conventional plastics fail. Its combination of thermal stability, chemical resistance, dimensional stability, and tribological performance has cemented its place in aerospace, automotive, electronics, and industrial sectors. And with continued advances in reinforcement technologies (e/g/, carbon fiber, lubricated fillers), PPS will expand into even more demanding applications, offering engineers a versatile material platform for the future.
If you are interested in PPS as a material for one of your designs, contact the experts at Advanced EMC.

