by Sara McCaslin, PhD Sara McCaslin, PhD No Comments

Kynar: Its Properties and Uses

Kynar is a high-performance PVDF fluoropolymer known for its strength, chemical resistance, and excellent durability in harsh environments. Engineers rely on it for applications where purity, stability, and reliable long-term performance are essential. This blog post takes a close look at its unusual properties and various uses.

What Is Kynar (PVDF)?

Kynar (PVDF) is a semi-crystalline fluoropolymer that comprises repeating vinylidene fluoride units. It has very strong carbon–fluorine (C–F) bonds, making it among the strongest bonds in organic chemistry. These strong (C–F) bonds give it excellent resistance to both environmental degradation and chemical attack. It also exhibits 50–60% crystallinity, which is responsible for its high tensile strength, good fatigue resistance, and excellent barrier properties. It also offers a unique balance of dimensional stability, rigidity, and toughness due to its crystallinity. 

How PVDF Compares to Other Fluoropolymers 

The fluoropolymer PVDF belongs to the same chemical family as PTFE, FEP, and PFA, but it has properties that set it apart. 

For example, PTFE offers superior high-temperature performance and chemical resistance, but it cannot be melt-processed as easily. PVDF, on the other hand, is fully melt-processable, which allows manufacturers to use conventional extrusion, injection molding, blow molding, and rotational molding equipment. This significantly lowers fabrication cost and opens the door to more complex shapes, thin-wall components, and high-volume production runs than PTFE can support.

While FEP and PFA are melt-processable like PVDF, they are more flexible and have lower mechanical strength. One of PVDF’s most significant engineering advantages is its higher modulus and strength compared to PTFE, FEP, or PFA. This makes it suitable for structural components where other fluoropolymers might be too soft. PVDF also offers significantly higher mechanical strength, good rigidity, and superior abrasion resistance while sharing the chemical and corrosion resistance of the fluoropolymer family. 

Its primary drawback is its constrained temperature range. PVDF does possess a broad service temperature window, typically −40°C to ~150°C, depending on grade. While this is lower than PTFE’s upper limit (~260°C), PVDF still possesses excellent rigidity within its working range. This rigidity helps maintain dimensional stability in pressurized systems, rotating equipment, and components exposed to mechanical loads, where PTFE may creep or cold-flow.

Key Material Properties of Kynar

Kynar has several key material properties that make it ideal for use in seals, gaskets, and o-rings, as well as bearings, linings, barriers, cable jacketing, and more. 

Mechanical Properties

Among fluoropolymers, Kynar is known for its high tensile strength, toughness, and stiffness as well. It also has good resistance to wear and abrasion, as well as excellent fatigue performance and resistance to both flexural and tensile creep, contributing to its suitability to seal and bearing applications.

Thermal Properties

As mentioned earlier, the service temperature range of Kynar is −40°C to ~150°C, depending on the grade. It is also naturally flame-resistant, and a UL94 V-0 grade is available. Additionally, Kynar has low thermal conductivity, which is one reason it is often chosen for barrier or insulating applications. It also exhibits excellent thermal stability during temperature changes.

Chemical Resistance

Kynar exhibits outstanding resistance to acids, bases, halogens, and solvents (alcohols, ketones, and esters) as well as a number of hydrocarbons and fuels. In addition, possesses exceptional resistance to permeation, which can be a critical factor in chemical handling and semiconductor applications.

Electrical Properties

Kynar has a high dielectric strength and stable insulating performance across a wide range of frequencies, making it an ideal choice for electrical insulation and jacketing.

Nuclear Properties

Kynar is highly stable in radiation-rich environments, a feature that makes it particularly suitable for space and nuclear applications. In such applications, it is used for seal jacketing, sensor housings, and cooling water systems, among others.

UV and Weatherability

Kynar exhibits excellent outdoor performance because of its natural resistance to UV, ozone, and gamma radiation, as well as its environmental stability. In addition, it is resistant to the formation of fungus. Its long service life in such environments has made it a proven material for use in architectural cladding and wire insulation. 

Purity and Low Extractables

Naturally low levels of ionic contamination have long made Kynar an excellent choice for semiconductor wet-process systems and high-purity chemical handling. In addition, due to its low outgassing, Kynar exhibits minimal weight loss under high-vacuum conditions.

Processability Advantages

Kynar is exceptionally easy to process, with very little specialized equipment required, and applicable manufacturing methods include injection molding, extrusion, welding, compression molding, and rotational molding, making it far more processable than PTFE. This is due in part to Kynar’s wide processing window.

Conclusion

Kynar has is a trusted engineering polymer. It it delivers stable, long-lasting performance in demanding environments. It maintains dimensional stability under load, provides reliable sealing when used in PVDF-based components, and offers a rare combination of strength, chemical resistance, and ease of processing. With properties such as a wide operating temperature range, strong fatigue resistance, and naturally high purity, Kynar supports applications across chemical processing, semiconductors, aerospace, and energy. Its blend of durability, stability, and manufacturability makes it a reliable choice across industries.

Contact Advanced EMC for customized Kynar components, seals, and bearings, as well as general guidance on PVDF material selection.

by Sara McCaslin, PhD Sara McCaslin, PhD No Comments

Wear and Friction in Polymer Bearings

When bearings fail, friction and wear are often the primary causes. Friction and wear in polymer bearings are critical factors in their design and performance. In fact, friction and wear influence everything from energy efficiency to service life. 

In this article, we examine the fundamentals of friction and wear, their impact on polymer bearing performance, and why understanding PV values is crucial for selecting the appropriate material. Whether you work in aerospace, medical devices, or industrial automation, this guide will help you make informed engineering decisions.

Understanding Friction

One way to define friction is the resistive force that occurs when two surfaces move against each other. In the context of polymer bearings, friction plays a key role in determining energy efficiency, heat generation, and overall wear behavior. 

Friction arises from surface interactions at the microscopic level. Even polished surfaces have asperities (tiny peaks and valleys) that cause mechanical interlocking and adhesion. In polymer bearings, friction behavior is influenced not only by surface roughness and contact pressure but also by factors such as lubrication, temperature, and material composition. The table below summarizes the main friction mechanisms at work in polymer bearings.

MechanismDescription
AdhesionIntermolecular bonding between polymer and counterface contributes to resistance.
Surface DeformationPolymer deforms under load during sliding, adding to frictional resistance.
Viscoelastic DissipationInternal energy loss from viscoelastic behavior increases the friction coefficient.
Transfer Film FormationA layer of polymer transfers to the counterface, altering friction over time.
Stick-Slip PhenomenonAlternating adhesion and sliding causes vibrations or unstable motion.
Surface Roughness/TextureMicrostructure of surfaces influences contact area and frictional behavior.

High friction in polymer bearings can lead to excessive heat buildup, accelerated wear, and energy loss in mechanical systems. However, polymers often offer lower coefficients of friction than metals, which makes them an excellent option for reducing drag and operating efficiently without the need for continuous lubrication. This is especially advantageous in applications where maintenance access is limited, the environment is cryogenic, or cleanliness and sanitation are critical.

Understanding Wear

Wear is the gradual removal or deformation of material at solid surfaces due to mechanical action. In polymer bearings, wear not only affects part longevity but can also significantly alter dimensions and negatively impact performance over time, potentially leading to even increased friction, misalignment, or failure.

Wear occurs through various mechanisms, including abrasion, adhesion, fatigue, and erosion. In polymer bearings, the dominant type of wear often depends on operating conditions such as load, speed, temperature, and the presence (or absence) of lubricants. The main wear types are summarized in the table below.

Wear TypeDescriptionCommon CausesRelevance to Polymers
Abrasive WearHard particles or rough surfaces wear away material.Contaminants, rough counterfaces, high contact stressCommon in dirty or poorly filtered environments.
Adhesive WearSurfaces bond at contact points and then tear apart during movement.High pressure, poor lubricationCan be minimized by using low-friction polymer grades.
Fatigue WearCracks form due to repeated cyclic loading, leading to material removal.Repeated loading/unloading cyclesImportant for dynamic applications (e.g., pumps).
Erosive WearMaterial is gradually removed by impact from particles or fluid flow.High-speed fluids with particulatesLess common, but relevant in slurry or fluid transport.

Polymers typically have a lower elastic modulus and can deform under load, which helps reduce localized stress and delay wear, provided the material is selected correctly and the PV value remains within limits.

Friction and Wear in Polymer Bearings

Polymer bearings behave differently than metal under friction and wear. Their unique tribological properties—including low friction coefficients, self-lubricating capabilities, and tolerance for misalignment—make them ideal for applications where conventional metal bearings would struggle to perform.

PV Value: What It Means and Why It Matters

A key metric used in evaluating polymer bearing performance is the PV value, which stands for Pressure × Velocity. It quantifies the combination of load (P, in psi or MPa) and surface speed (V, in ft/min or m/s) that a bearing can withstand before experiencing excessive wear or thermal failure. In general, higher PV values indicate that the bearing can withstand greater stress and speed. Exceeding the limiting PV can lead to thermal softening, deformation, or accelerated wear of the polymer material.

Every polymer material has a limiting PV, which is the maximum combination of pressure and velocity it can handle under steady conditions. Engineers must stay below this threshold when designing systems to prevent performance breakdowns. Factors that affect limiting PV include:

  • Material type (e.g., PTFE, PEEK, UHMW)
  • Lubrication conditions
  • Heat dissipation
  • Bearing geometry and clearance

Choosing a polymer with a suitable PV rating is essential when operating at high loads, high speeds, or both. Some high-performance polymers even incorporate fillers—such as glass, carbon, or graphite—to increase wear resistance and raise the limiting power-to-weight (PV) threshold. Typical values are in the table below.

MaterialCoefficient of FrictionWear ResistanceLimiting PVTypical Enhancements
PTFEVery Low (0.05–0.10)FairLowGlass, bronze, or carbon fillers
PEEKModerate (0.15–0.30)ExcellentHighCarbon fiber, PTFE, graphite
UHMW-PELow (0.10–0.20)GoodModerateUV stabilizers, glass fiber
Nylon (PA)Moderate (0.15–0.25)Good (in dry conditions)Moderate to High (with lube)Moly disulfide
Filled PTFEVery Low (0.04–0.09)GoodModerateGraphite, MoS₂, or glass fiber blends
Polymer Beads

Choosing the Right Polymer for Friction and Wear

Selecting the optimal polymer for a bearing application requires more than just knowing the coefficient of friction. It involves understanding how various operating conditions interact with the material’s tribological profile.

Here are the major factors engineers should consider:

Load and Speed (PV Value): The combined pressure and velocity—expressed as the PV value—should stay below the material’s limiting PV to prevent overheating, deformation, or rapid wear. For high-load, high-speed applications, advanced materials like PEEK or filled PTFE are often necessary.

Temperature Range: Thermal stability varies widely across polymers. PEEK and PTFE perform well in high-temperature environments, while materials like UHMW-PE or nylon may soften or creep under prolonged exposure to heat.

Lubrication Conditions: Some applications operate with continuous lubrication, while others require dry-running performance. PTFE and UHMW-PE offer excellent dry lubricity, making them ideal for maintenance-free or clean-room conditions.

Chemical Exposure: Exposure to aggressive chemicals or cleaners can cause degradation of many plastics. PTFE offers broad chemical resistance, while nylon and acetal may be more limited depending on the environment.

Wear Resistance and Service Life: If durability is a primary concern, choose polymers that exhibit low wear rates under dynamic conditions. Fillers such as carbon fiber, glass, and graphite can significantly improve wear resistance without sacrificing too much in terms of friction.

Cost and Availability: High-performance polymers, such as PEEK and specialty-filled PTFE blends, come at a cost, however. For less demanding applications, materials like nylon or acetal may offer a more cost-effective solution.

Conclusion

Friction and wear are critical in polymer bearing design and specification. These factors directly impact performance, efficiency, and service life. Understanding how such friction and wear operate, along with the impact of PV value, temperature, lubrication, and material composition on behavior, empowers engineers to make informed decisions. Whether the application requires high-speed, dry-running conditions or chemical resistance in a corrosive environment, selecting the right polymer is crucial. At Advanced EMC Technologies, we specialize in high-performance polymer solutions engineered for demanding tribological environments. Contact us today to find the right material for your next bearing application.