by Sara McCaslin, PhD Sara McCaslin, PhD No Comments

Why PTFE Keeps Winning: The Material Science Behind High-Reliability Seal Solutions

Some materials survive extreme environments while others redefine what “extreme” means. From cryogenic hydrogen at -459°F to continuous operating temperatures of 500°F, from high-speed rotary shafts approaching 100,000 RPM to chemically aggressive process media, modern sealing applications demand more than incremental improvement. They demand stability, predictability, and performance under conditions where traditional elastomers begin to fail.

PTFE seals occupy that space.

This article examines why PTFE continues to be specified in aerospace, chemical processing, food and pharmaceutical systems, and high-speed rotary equipment. This article explores its extreme temperature stability, low-friction tribological behavior, chemical inertness, high-speed capability, long-term reliability, and the ability to tailor performance through fillers and spring energization. The goal is not simply to list advantages, but to understand how those properties translate into measurable engineering performance.

Extreme Temperature Stability

One of the properties that sets PTFE seals apart is their ability to maintain mechanical integrity across a wide range of temperatures, from -459°F (-273°C) to +500°F (+260°C). In addition, they resist melting and degradation at continuous operating temperatures of 500°F, including spikes up to 600°F. High temperatures are not the only area where PTFE excels. PTFE seals remain flexible and retain sealing force even in the presence of cryogenic fluids (e.g., liquid hydrogen, deep space). They successfully prevent the embrittlement problems that are so common in traditional elastomeric seal solutions. In addition, PTFE has a very low coefficient of thermal expansion that supports dimensional stability even during rapid temperature cycling.

Superior Tribological Properties

PTFE also offers an extremely low coefficient of friction, as low as 0.04. This property reduces torque requirements and power loss. PTFE also deposits a microscopic film on the mating surface, creating a PTFE-on-PTFE interface that minimizes wear and enables dry running. Dry running is an extremely useful feature of PTFE, meaning it can run without external lubrication and eliminate stick-slip even after long periods of inactivity. 

Chemical and Environmental Resistance

PTFE is one of the most chemically non-reactive polymers. It is non-reactive with almost all industrial chemicals, including aggressive acids (hydrochloric and sulfuric), solvents, and hydrocarbon fuels. Furthermore, it does not become brittle, swell, or degrade when it is exposed to corrosive media. Virgin PTFE grades are FDA, USDA, and 3-A Sanitary approved for food, dairy, and pharmaceutical use. PTFE is hydrophobic: it repels water and resists moisture buildup, making cleaning and sterilization much easier. Finally, PTFE is ideal for aerospace and high-vacuum environments because of its minimal outgassing, which prevents the contamination of sensitive optics or electronics.

High-Speed and Pressure Performance

PTFE rotary shaft seals can handle shaft surface speeds around 6,900 rpm and rotational speeds on the order of 100,000 RPM, which exceeds the limits seen in traditional elastomeric seals. They can also handle pressures up to 100-150 psi, and when BUR or sprig-energized options are used,, they can withstand significantly higher pressures. 

Operational Longevity and Reliability

PTFE seals have an unlimited shelf life, unlike traditional rubber seals, which age and degrade during storage. In addition, the self-lubrication and wear resistance of PTFE seals reduce unexpected downtime and maintenance downtime.  In addition, non-abrasive grades of PTFE can protect mating shafts from grooving and other surface damage that compromise seal performance. Finally, the low friction of PTFE reduces energy consumption. 

Customizability via Fillers and Design

Another key benefit of PTFE is that it can be compounded with fillers to target specific material properties. 

  • Glass Fiber: Increases wear resistance and compressive strength
  • Carbon/Graphite: Improves thermal conductivity and allows for use in steam/water, and is safer for softer shafts
  • Molybdenum Disulfide (MoS₂): Increases hardness and lubricity for high-pressure dry running
  • Polyimide: Ultra-low friction for use against soft mating surfaces like aluminum

In addition, metal springs can be added to provide a constant sealing force and compensate for seal wear, hardware misalignment, or thermal contraction.

Conclusion

In high-performance applications, failure rarely stems from a single variable. It emerges when materials, load, temperature, motion, and environment are not aligned. PTFE provides the stability needed to bring those variables into balance.

To learn more about PTFE options for sealing solutions, contact the PTFE seal experts here at Advanced EMC. We are here to help you from the initial design stages through to testing and implementation.

by Sara McCaslin, PhD Sara McCaslin, PhD No Comments

Surface Finish, Hardness, and Coatings: The “Quiet” Variables That Make PTFE Rotary Seals Live or Die

PTFE rotary shaft seals behave very differently from their elastomeric counterparts. Because one of their primary mechanisms is transfer film, they have different requirements related to the mating surface to achieve a successful solution. This blog post looks at three key factors that impact the performance of PTFE rotary shaft seals: surface finish, hardness, and coating.

Surface Finish

For PTFE rotary shaft seals, surface finish is extremely important. To achieve the least possible friction with a PTFE seal, the mating surface needs a specific texture. The mating surface must be rough enough to abrade a microscopic amount of PTFE to form a transfer film during the break-in period. This transfer film achieves a PTFE-on-PTFE effect, resulting in extremely low friction. 

If the surface finish is too smooth, on the order of <2µm Ra, the transfer film will not adhere. To make matters worse, the seal lip will hydroplane, experience stick-slip friction, and generate significant heat that can char the lip.The surface finish can be too rough, as well. If the surface is > 4µm Ra, the shaft will act like a file, abrading the seal lip faster than the transfer film can form. This damages the seal itself and causes leakage.And while Ra is key, Rs (Skewness) is also important. The goal is to achieve negative skew so the surface has plateaus and valleys rather than sharp peaks that can slice the seal. 

In addition, if the shaft is finished using a standard turning process, it may look perfect, but result in mysterious leaks. During standard turning, microscopic helical grooves are left in the shaft material. The grooves are like the threads of a screw, and during rotation they can pump oil under the seal through this micropump effect. The industry standard for PTFE is a plunge-ground finish, which ensures that marks from turning and grinding are circumferential, eliminating the pumping effect. 

Hardness

PTFE is a soft material that normally would not damage a metal surface, but virgin PTFE is rarely used for a rotary shaft seal. In such cases, PTFE is filled with glass fibers, bronze, carbon, or graphite — all abrasive fillers — to improve structural integrity and sealing performance. If the shaft is softer than these fillers, the seal will wear a groove into the shaft and leak. To prevent this, experts recommend a mating surface with a hardness of 55-65 HRC (Rockwell C).

Surface Coatings

Surface coatings on the mating surface are often used to achieve the required hardness or to repair a worn shaft, but this can lead to issues if not done correctly. PTFE is an excellent thermal insulator, and PTFE rotary shaft seals depend on the shaft to conduct away the heat generated by friction. Some ceramic coatings are also thermal insulators, and when used they can trap heat at the seal interface. This can lead to a rise in temperature that softens the PTFE and leads to seal failure.

For such reasons, many engineers will use hard chrome as the shaft coating because it is both hard and thermally conductive. Another option is DLC (Diamond-Like Carbon), which has sufficient hardness to prevent grooving and an extremely low coefficient of friction that significantly reduces heat buildup at the lip of the PTFE seal.

Conclusion

Because PTFE rotary shaft seals are fundamentally different from their elastomeric counterparts, they have different requirements for the mating surface. For a successful sealing solution, engineers must consider the surface finish, hardness, and coatings or run the risk of leaks.
If you need a dynamic sealing solution, consider PTFE rotary shaft seals. Contact us today to learn more about your options and how Advanced EMC can support you design needs.