by Sara McCaslin, PhD Sara McCaslin, PhD No Comments

Harsh Chemical Environments: Why Polymer Seals Outperform Metal

In industries where equipment is constantly exposed to harsh chemical environments, corrosion is a leading cause of premature seal failure, unplanned downtime, and costly maintenance. Even with protective coatings and careful material selection, metal is still vulnerable to pitting, stress corrosion cracking, and galvanic attack.

Certain engineering polymers are inherently resistant to the many forms that chemical degradation can take. They provide a proven and reliable solution to sealing even in some of the most corrosive environments. 

This article reviews the basics of corrosion, explains why corrosion is not a problem for polymers, and discusses the most common engineering polymers used in sealing solutions.

Metals Sealing Solutions and Corrosion

Metal seals used to be chosen for their strength and rigidity, but their metallic composition makes them susceptible to various forms of corrosion. For example, uniform corrosion can occur when the entire surface is exposed to a reactive chemical, causing the material to gradually thin. Another example is pitting corrosion, which is very common in chloride-rich or acidic environments. This type of corrosion generates localized damage that can quickly compromise sealing integrity.

Galvanic corrosion is another issue, especially when dissimilar metals come into contact in the presence of an electrolyte. In addition, stress corrosion cracking can occur when tensile stress and a corrosive atmosphere act together, leading to sudden and unexpected failure. Once corrosion begins, sealing forces diminish, leakage risk increases, and imminent failure awaits if the seal is not replaced proactively.

Why Polymers Excel in Harsh Chemical Environments

Polymers do not experience galvanic corrosion because they are non-conductive. In addition, some high-performance polymers (e.g., PTFE) are chemically inert, meaning they will not react with acids, bases, or solvents. This level of chemical stability allows them to maintain their dimensions and mechanical properties even after years of exposure to aggressive media. When used with compatible chemicals, several engineering polymers do not experience pitting or stress corrosion cracking. 

In addition to corrosion resistance, polymers offer low friction and reduced wear rates, which can extend the service life of both the seal and the mating surface. Some, like PTFE and UHMW-PE, provide self-lubricating properties that enable dry running. Their lighter weight can also benefit marine and transportation applications where every pound matters.

Polymer Beads

Commonly Used Materials for Seals in Harsh Chemical Environments

PTFE (Polytetrafluoroethylene)

PTFE (commonly known as Teflon) is one of the most widely used polymers for seals due to its exceptional chemical resistance, extremely low friction, and broad operating temperature range from -200°C to +260°C. It remains stable in the presence of almost all industrial chemicals, making it ideal for O-rings, gaskets, and dynamic seals used in even the most aggressive environments.

PEEK (Polyetheretherketone)

PEEK is a go-to choice for sealing applications that demand both chemical resistance and mechanical strength under high temperature and pressure. It maintains integrity in aerospace, oil and gas, and chemical processing environments where seals are subjected to extreme loads and aggressive media.

Hytrel (Thermoplastic Polyester Elastomer)

Hytrel has an unusual combination of flexibility with chemical resistance, making Hytrel sealing solutions exhibit reliable performance across a wide temperature range. It is commonly used in automotive, hydraulic, and pneumatic seals where both elasticity and resistance to fuels, oils, and industrial fluids are critical.

Kynar (Polyvinylidene Fluoride, PVDF)

Kynar, sometimes referred to as PVDF, provides excellent resistance to acids, bases, and organic solvents. Its stability under long-term chemical exposure makes it a reliable material for seals and gaskets in chemical processing equipment, including pumps, valves, and pipelines.

PPS (Polyphenylene Sulfide)

PPS offers high-temperature capability and chemical resistance, making it a strong candidate for sealing in automotive and industrial applications where both thermal cycling and aggressive fluids are present. It retains dimensional stability and mechanical performance under prolonged exposure to harsh conditions.

Performance Benefits in Harsh Chemical Environments

Polymer sealing solutions can avoid the problematic degradation mechanisms plaguing traditional metal seals. Corrosion immunity combined with other key seal properties allows them to maintain sealing pressure and integrity over more extended periods, reducing the frequency of replacements. Also, lower maintenance requirements translate into both cost savings and less downtime.

Materials with dry-running capability, such as PTFE or filled PEEK, allow operation without lubrication. This can be critical in environments where lubricants could be washed away or contaminated. In aerospace systems, the weight savings from polymer components alone can improve energy efficiency and handling.

Conclusion

When corrosion is a constant threat, polymer seals offer a long-lasting, low-maintenance alternative to traditional metal designs. The chemical resistance, dimensional stability, and low-friction properties of engineering polymers make them ideal as sealing solutions for harsh chemical environments. By specifying polymer seals early in the design phase, engineers can improve system reliability, reduce downtime, and lower lifetime costs.

Contact Advanced EMC or request a quote to discuss polymer sealing solutions engineered for your specific operating conditions and chemical challenges.

by Sara McCaslin, PhD Sara McCaslin, PhD No Comments

Spring-Energized Seals & Extreme Environments

Sealing components face relentless stress in environments where extremes are the norm. This is true whether in outer space, deep underwater, or inside a high-temperature reactor. Temperatures can swing, pressures can reach incredible levels, and exposure to corrosive chemicals or radiation might occur daily. In such conditions, failure is costly and can be catastrophic. And that is where spring-energized seals come in.

This article explores how PTFE spring-energized seals provide a robust and reliable solution for sealing in extreme environments. We will examine the specific challenges and explain why spring-energized seal technology is critical for mission success, especially when paired with high-performance polymers like PTFE.

Extreme Environments and Their Sealing Challenges

Designing reliable seals for extreme environments requires an in-depth understanding of the forces at play. In many mission-critical systems, failure is not an option. However, high temperatures, aggressive chemicals, radiation, and pressure differentials constantly threaten seal integrity. Below is a closer look at the environmental factors that make sealing so demanding.

Temperature Extremes

High Temperatures

Seals exposed to elevated temperatures face thermal expansion, loss of elasticity, material degradation, and increased wear. Standard elastomers may soften, creep, or chemically break down under continuous thermal stress, leading to leakage or failure. 

Cryogenic Temperatures

At the opposite end of the thermal spectrum, cryogenic conditions pose equally complex problems. Materials may contract significantly, lose ductility, and become brittle. Traditional seals can shrink away from sealing surfaces in these conditions, resulting in leaks. 

High Pressure

Systems operating under extreme pressure are subject to tremendous mechanical stress. Without the right materials and geometry, seals permanently deform or lose contact with the sealing surfaces. Maintaining long-term reliability in such environments requires mechanically reinforced and dimensionally stable seals.

Chemical Exposure

Corrosive Media

Many industrial applications involve aggressive chemicals that quickly degrade standard elastomers and plastics. Exposure to acids, solvents, fuels, and other corrosive substances can cause swelling, embrittlement, or chemical attack.

Outgassing

Even trace amounts of outgassed compounds from seal materials can cause severe contamination in ultra-clean or vacuum environments. Outgassing is especially problematic when organic compounds interfere with optics, electronics, or surface chemistry. This means that seals in these environments must be made from materials with exceptionally low volatility and minimal extractables.

Radiation

Radiation is another factor that compromises many polymers’ structural integrity and performance. In nuclear and aerospace environments, ionizing radiation can cause chain scission or crosslinking, leading to embrittlement, cracking, and dimensional instability. Seals used in these settings must resist exposure to short- and long-term radiation without degrading.

PTFE Spring-Energized Seals: A Solution Built for Extremes

Sealing in harsh environments demands more than just durability. It requires materials and designs that actively maintain sealing force under fluctuating or extreme conditions. And that is precisely where PTFE spring-energized seals excel.

What Is a PTFE Spring-Energized Seal?

A spring-energized seal consists of two core components: a polymer jacket and an internal energizing spring. The jacket provides chemical resistance and mechanical barrier properties. The spring, on the other hand, ensures consistent contact pressure against the sealing surface, even when temperatures, pressures, or mechanical conditions change.

As conditions shift, the spring compensates for pressure or material contraction changes, keeping the seal engaged. This challenge makes spring-energized seals ideal for dynamic sealing applications, including reciprocating and rotary motion.

Spring types include:

  • Cantilever springs – Ideal for low to moderate pressures and cryogenic environments
  • Helical or coil springs – Used for higher pressures and more demanding mechanical loads
  • Canted coil springs – Suitable for sealing and electrical conduction, where uniform force is critical

Why Use PTFE for the Spring-Energized Seal Jacket?

Polytetrafluoroethylene (PTFE) is one of the most chemically resistant and thermally stable materials. And it exhibits a unique combination of properties that make it well-suited for extreme environments:

  • Broad Temperature Range: PTFE maintains performance from cryogenic levels (below -250°F) to elevated temperatures exceeding 500°F.
  • Chemical Inertness: It resists nearly all corrosive media, including strong acids, bases, fuels, and solvents.
  • Low Friction Coefficient: Ideal for dynamic applications where smooth, wear-resistant motion is essential.
  • Non-outgassing: PTFE has minimal extractables, making it suitable for ultra-clean vacuum or space environments.
  • Radiation Resistance: Certain PTFE formulations offer resistance to ionizing radiation.
  • Compliant with Regulatory Standards: Variants of PTFE that meet FDA, USP Class VI, and semiconductor purity standards are available.

When combined with the appropriate spring energizer, a PTFE seal delivers a balance of chemical resistance, mechanical compliance, and thermal stability that is difficult to match with conventional elastomers or plastic seals.

Benefits of PTFE Spring-Energized Seals

PTFE spring-energized seals offer a range of performance advantages that make them indispensable in extreme operating conditions. Unlike conventional elastomeric seals, they are engineered to maintain tight sealing integrity across wide temperature and pressure ranges while resisting chemical and mechanical degradation.

Reliable Sealing Across Variable Conditions with Spring-Energized Seals

The built-in energizing spring provides consistent contact pressure even when temperatures fluctuate or the sealing surfaces shift due to thermal cycling or pressure changes. Because of this active sealing force, the seal ensures leak-tight performance in static and dynamic applications, whether in cryogenic fuel systems or high-pressure hydraulic actuators.

Exceptional Chemical Compatibility with PTFE

PTFE’s chemical inertness allows these seals to withstand aggressive fluids such as acids, fuels, solvents, and oxidizers. They are widely used in chemical processing, aerospace fuel systems, and pharmaceutical manufacturing—anywhere seal failure from chemical attack would be catastrophic.

Thermal Stability and Cryogenic Performance of PTFE Spring-Energized Seals

With a temperature tolerance ranging from below -250°F to above 500°F, PTFE spring-energized seals outperform most other sealing materials. They maintain flexibility and sealing force in cryogenic applications and do not degrade under high thermal loads.

Low Friction and Wear Resistance

PTFE’s low coefficient of friction minimizes heat generation and wear in dynamic sealing applications, which is especially important in systems requiring precise motion control or long service intervals, such as medical devices or aerospace actuators.Long Service Life

The combination of a resilient spring and a chemically inert jacket gives spring-energized seals excellent durability, even under continuous mechanical and thermal stress. This results in reduced downtime, fewer seal replacements, and lower maintenance costs over the lifecycle of the equipment.

Design Flexibility of Spring-Energized Seals

Spring-energized seals can be tailored for specific performance requirements, including:

  • Spring force
  • Seal geometry
  • Jacket fillers (e.g., glass, carbon, molybdenum disulfide)
  • Regulatory compliance (FDA, USP, NSF, etc.)

This level of customization ensures that each seal is optimized for its intended environment and operational demands.

Oil and Gas Industry During COVID-19

Applications of Spring-Energized Seals in Extreme Conditions

Because of their resilience and adaptability, engineers use PTFE spring-energized seals across a wide range of industries where standard sealing solutions cannot survive. These applications are defined by extremes—whether of temperature, pressure, chemical exposure, or environmental cleanliness.

Aerospace

In aerospace systems, seals must withstand extreme temperature variations, exposure to high-altitude vacuum conditions, and, in some cases, radiation. Engineers use PTFE spring-energized seals in fuel systems, cryogenic propulsion lines, actuators, and cabin pressure systems. Their low outgassing properties make them suitable for spacecraft and satellite environments.

Oil and Gas

Oilfield equipment routinely faces high-pressure differentials, corrosive drilling fluids, and wide temperature swings, from surface operations to downhole tools. Spring-energized seals made with chemically resistant PTFE compounds are commonly used in valves, pumps, and logging tools to maintain long-term sealing integrity under these harsh conditions.

Semiconductor Manufacturing

The semiconductor industry demands ultra-clean conditions where even minor contamination can lead to costly defects. PTFE seals are ideal for vacuum and plasma environments due to their low outgassing characteristics and resistance to aggressive process chemicals. Engineers use these seals in wafer handling systems, etching tools, and deposition chambers.

Medical and Pharmaceutical Equipment

Sealing solutions must be chemically inert, biocompatible, and often sterilizable in medical and pharmaceutical applications. Engineers integrate PTFE spring-energized seals in drug delivery systems, diagnostic devices, and sterile processing equipment where cleanliness, chemical resistance, and regulatory compliance are paramount.

Defense and Nuclear

Exposure to ionizing radiation, pressure cycling, and high temperatures is common in defense and nuclear environments. PTFE spring-energized seals are chosen for these applications because they maintain mechanical integrity under radiation and resist degradation over long periods of use. Applications include missile systems, nuclear reactor controls, and radiation-shielded enclosures.

Spring-Energized Seals are Ideal for Harsh Environments

Sealing in extreme environments—whether it involves intense heat, deep cryogenics, corrosive chemicals, or high-radiation fields—requires more than conventional materials and designs. PTFE spring-energized seals provide a proven solution engineered to withstand the most demanding conditions across aerospace, oil and gas, semiconductor, medical, and nuclear applications.

Combining the chemical inertness and thermal stability of PTFE with the adaptive force of a spring energizer, these seals maintain tight, reliable performance where others fail. Their low friction, minimal wear, and customizability make them the preferred choice for mission-critical systems where failure is not an option.

If you are facing extreme sealing challenges, trust the experts at Advanced EMC. Our PTFE spring-energized seals are engineered for durability, precision, and performance, no matter how harsh the environment. Contact us today to find the right sealing solution for your application.