by Daniel Mays Daniel Mays No Comments

Machined and Molded Polymer Bearings: Nylon 66, PEEK, and PPS

Nylon 66, PEEK, and PPS are available in bearing grades, but how should they be manufactured? The choice of manufacturing method can have a significant impact on their tolerances, performance, and cost. 

This blog post focuses on machined and molded polymer bearings, including their benefits and limits, how they compare to metal options, and the best ways of manufacturing bearings made from three very different materials: Nylon 66, PEEK, and PPS. 

Introduction to Polymer Bearings

Polymer bearings are low-friction, lightweight alternatives to traditional bearings. They are corrosion-resistant and offer varying degrees of chemical resistance. Polymer bearings are also known for their ability to run dry or with minimal lubrication, as well as good wear characteristics. They are also electrically insulating and offer quieter operation than their metal counterparts.

However, polymer bearings do have their limits. They are more susceptible to thermal expansion and may have lower load limits and PV than their metal counterparts, but the addition of fillers can mitigate this issue. In some cases, they may be susceptible to moisture uptake. 

The table below summarizes the major differences between metal and polymer bearings.

Metal vs Polymer Bearings

FeatureMetal BearingsPolymer Bearings
FrictionLow only with lubricationLow due to inherent lubricity
LubricationRequiredOften not required
Wear MechanismAbrasive/adhesive fatigueTransfer film formation
CorrosionPossibleNearly immune
Shock/VibrationNo dampingNatural damping
SpeedHighModerate
LoadHigherModerate
Temperature LimitsExcellentVaries by polymer
MaintenanceHigherVery low

Machined vs. Molded Polymer Bearings

Machined bearings are best for small production runs where tight tolerances and complex geometries are involved, and machining is ideal for prototypes, custom components, and specialty rotating equipment. This approach to manufacturing bearings also allows the material to remain homogenous with no molded-in stresses.

Molded bearings are the best option for high-volume production, and they are more cost-effective for simpler geometries. Molding also means reduced part-to-part variation; however, molded-in stress may be present, and there are limits to surface finish.

When choosing between machined and molded polymer bearings, the key factors are:

  • Geometry
  • Tolerances
  • Cost
  • Production volume

Nylon 66, PEEK, and PPS

Among the various options for polymer bearings are Nylon 66, PPS, and PEEK. The table below summarizes the differences between these materials.

Performance Comparison: Nylon 66 vs. PPS vs. PEEK

Property / FactorNylon 66PPSPEEK
Max Continuous Use Temperature~100–120°C~200–220°C~240–260°C
Wear ResistanceGood (improved with lubrication)Very goodExcellent (especially filled grades)
FrictionLowLowVery low
Moisture AbsorptionHigh (can swell, affects tolerances)Very lowVery low
Dimensional StabilityModerate (affected by humidity)HighVery high
Chemical ResistanceModerateExcellentExcellent
Mechanical StrengthGoodHighVery high
Impact ResistanceVery goodModerateGood
Creep ResistanceModerateGoodExcellent
PV CapabilityLow–MediumMedium–HighHigh–Very High
CostLowMediumHigh
Machining SuitabilityExcellentExcellentExcellent (best with filled grades)
MoldabilityExcellentGoodGood
Typical ApplicationsRollers, appliance bearings, automotive interior componentsPumps, compressors, chemical processing, precision housingsAerospace, oil & gas, high-speed bearings, semiconductor tools

Manufacturing Nylon 66, PEEK, and PPS Bearings

There are several different bearing materials available, but of interest in this blog post are Nylon 66, PPS, and PEEK bearings.

Nylon 66

Nylon 66 is very easy to mold because of its low viscosity, forging processing window, and good flow characteristics. However, there is going to be high mold shrinkage, which requires careful part design to keep warpage under control. Nylon also absorbs moisture, which means that drying is important before molding takes place. 

Nylon also machines easily, but its high ductility leads to stringy chips that necessitate the use of chip-breakers. Heat buildup is also an issue with nylon, and moisture absorption can impact the level of precision that can be achieved. It does, however, respond well to secondary machining on already molded parts, but does not work well with tight-tolerance CNC components.

PEEK

Because PEEK high a high melt temperature around 343°C, a very narrow thermal window that requires precision temperature control, and requires a heated mold, it is considered challenging to mold. However, with the right processing parameters and careful design, PPS can be molded and can manufacture parts with excellent thermal and mechanical performance (but is more expensive). 

PEEK is very difficult to machine. Its high modulus and hardness make it especially tough on cutting tools, and reinforced grades can be highly abrasive. It also generates an abundance of heat, thus requiring the use of coolants. However, machining PEEK supports excellent tolerances and surface finishes when the right combination of feed and speed is used. In fact, PEEK is frequently machined for low-volume aerospace and medical components.

PPS

PPS is not as easy to mold as Nylon 66 because its melt temperature is higher, it possesses a narrower processing window, and has high viscosity. However, it does exhibit very low shrinkage and excellent dimensional stability. PPS molding is very predictable and an excellent option once the right processing parameters have been figured out.

PPS is machinable, definitely more so than Nylon, but tends to be more brittle. It produces short chips and there is a risk of edge chipping during more aggressive cuts. On the other hand, it is good for tight tolerances. Note that filled grades of PPS can accelerate tool wear. Machining PPS is ideal for high-precision parts where dimensional stability is important.

Conclusion

Machined and molded Nylon 66, PPS, and PEEK bearings continue to gain traction because of properties such as low friction, wear characteristics, damping, corrosion resistance, and chemical compatibility. If you are in need of polymer bearings, Advanced EMC is here to help. Our team of engineers and bearing experts can help you from initial design to manufacturing to testing. Contact us today to learn more.

by Daniel Mays Daniel Mays No Comments

Kynar: Its Properties and Uses

Kynar is a high-performance PVDF fluoropolymer known for its strength, chemical resistance, and excellent durability in harsh environments. Engineers rely on it for applications where purity, stability, and reliable long-term performance are essential. This blog post takes a close look at its unusual properties and various uses.

What Is Kynar (PVDF)?

Kynar (PVDF) is a semi-crystalline fluoropolymer that comprises repeating vinylidene fluoride units. It has very strong carbon–fluorine (C–F) bonds, making it among the strongest bonds in organic chemistry. These strong (C–F) bonds give it excellent resistance to both environmental degradation and chemical attack. It also exhibits 50–60% crystallinity, which is responsible for its high tensile strength, good fatigue resistance, and excellent barrier properties. It also offers a unique balance of dimensional stability, rigidity, and toughness due to its crystallinity. 

How PVDF Compares to Other Fluoropolymers 

The fluoropolymer PVDF belongs to the same chemical family as PTFE, FEP, and PFA, but it has properties that set it apart. 

For example, PTFE offers superior high-temperature performance and chemical resistance, but it cannot be melt-processed as easily. PVDF, on the other hand, is fully melt-processable, which allows manufacturers to use conventional extrusion, injection molding, blow molding, and rotational molding equipment. This significantly lowers fabrication cost and opens the door to more complex shapes, thin-wall components, and high-volume production runs than PTFE can support.

While FEP and PFA are melt-processable like PVDF, they are more flexible and have lower mechanical strength. One of PVDF’s most significant engineering advantages is its higher modulus and strength compared to PTFE, FEP, or PFA. This makes it suitable for structural components where other fluoropolymers might be too soft. PVDF also offers significantly higher mechanical strength, good rigidity, and superior abrasion resistance while sharing the chemical and corrosion resistance of the fluoropolymer family. 

Its primary drawback is its constrained temperature range. PVDF does possess a broad service temperature window, typically −40°C to ~150°C, depending on grade. While this is lower than PTFE’s upper limit (~260°C), PVDF still possesses excellent rigidity within its working range. This rigidity helps maintain dimensional stability in pressurized systems, rotating equipment, and components exposed to mechanical loads, where PTFE may creep or cold-flow.

Key Material Properties of Kynar

Kynar has several key material properties that make it ideal for use in seals, gaskets, and o-rings, as well as bearings, linings, barriers, cable jacketing, and more. 

Mechanical Properties

Among fluoropolymers, Kynar is known for its high tensile strength, toughness, and stiffness as well. It also has good resistance to wear and abrasion, as well as excellent fatigue performance and resistance to both flexural and tensile creep, contributing to its suitability to seal and bearing applications.

Thermal Properties

As mentioned earlier, the service temperature range of Kynar is −40°C to ~150°C, depending on the grade. It is also naturally flame-resistant, and a UL94 V-0 grade is available. Additionally, Kynar has low thermal conductivity, which is one reason it is often chosen for barrier or insulating applications. It also exhibits excellent thermal stability during temperature changes.

Chemical Resistance

Kynar exhibits outstanding resistance to acids, bases, halogens, and solvents (alcohols, ketones, and esters) as well as a number of hydrocarbons and fuels. In addition, possesses exceptional resistance to permeation, which can be a critical factor in chemical handling and semiconductor applications.

Electrical Properties

Kynar has a high dielectric strength and stable insulating performance across a wide range of frequencies, making it an ideal choice for electrical insulation and jacketing.

Nuclear Properties

Kynar is highly stable in radiation-rich environments, a feature that makes it particularly suitable for space and nuclear applications. In such applications, it is used for seal jacketing, sensor housings, and cooling water systems, among others.

UV and Weatherability

Kynar exhibits excellent outdoor performance because of its natural resistance to UV, ozone, and gamma radiation, as well as its environmental stability. In addition, it is resistant to the formation of fungus. Its long service life in such environments has made it a proven material for use in architectural cladding and wire insulation. 

Purity and Low Extractables

Naturally low levels of ionic contamination have long made Kynar an excellent choice for semiconductor wet-process systems and high-purity chemical handling. In addition, due to its low outgassing, Kynar exhibits minimal weight loss under high-vacuum conditions.

Processability Advantages

Kynar is exceptionally easy to process, with very little specialized equipment required, and applicable manufacturing methods include injection molding, extrusion, welding, compression molding, and rotational molding, making it far more processable than PTFE. This is due in part to Kynar’s wide processing window.

Conclusion

Kynar has is a trusted engineering polymer. It it delivers stable, long-lasting performance in demanding environments. It maintains dimensional stability under load, provides reliable sealing when used in PVDF-based components, and offers a rare combination of strength, chemical resistance, and ease of processing. With properties such as a wide operating temperature range, strong fatigue resistance, and naturally high purity, Kynar supports applications across chemical processing, semiconductors, aerospace, and energy. Its blend of durability, stability, and manufacturability makes it a reliable choice across industries.

Contact Advanced EMC for customized Kynar components, seals, and bearings, as well as general guidance on PVDF material selection.